This review provides a concise historical overview of nitride SSEs, followed by a summary of recent key advances in their materials, crystal and local structures, and synthesis methods, with an emphasis on the fundamental understanding of lithium-ion diffusion mechanisms.
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Abstract Sulfone-based electrolyte (SL) as a novel type electrolyte for lithium-ion batteries (LIBs) has attracted increasing attention due to its exceptional high-voltage stability
Abstract Nitride solid-state electrolytes (SSEs) hold significant potential for addressing critical interfacial issues between SSEs and lithium metal in all-solid-state lithium metal batteries. These batteries are at the forefront of energy
However, the inherent high reduction potential of halide electrolytes remains a critical bottleneck, limiting their practical performance. This work focuses on cost-effective
Based on the previous theoretical understanding and analysis, the strategies of using lithium nitride to construct solid electrolyte interlayers on the surfaces of lithium metal
An amorphous nitrogenchloride dual-anion solid-state electrolyte (Li 1.3 ZrN 0.4 Cl 4.1) with high ionic conductivity (3.01 mS cm −1 at 25 °C) and broad electrochemical stability
To fully realize the potential of LATP-based solid-state lithium batteries, further exploration into the design of more ideal intermediate layers is essential. Herein, a lithiophilic interface strategy is
Abstract Solid electrolytes (SEs) in all-solid-state batteries (ASSBs) are garnering considerable attention for their potential applications in next-generation energy
This new β-Li3N solid-state electrolyte demonstrates a vacancy-mediated superionic diffusion mechanism, achieving high ionic conductivity (2.14 × 10−3 S cm−1) and effectively suppressing
Nitride solid-state electrolytes (SSEs) hold significant potential for addressing critical interfacial issues between SSEs and lithium metal in all-solid-state lithium metal batteries.
Abstract In the quest to enhance the safety of lithium-ion batteries, substantial research is underway to develop all-solid-state batteries, facing challenges in achieving high ion conductivity in solid electrolytes. This
Based on these insights, we offer perspectives on the future opportunities and directions for the advancement of nitride SSEs in all-solid-state lithium metal batteries.
Overall, nitride-based SSEs offer a promising pathway to miti-gate interfacial issues between the electrolyte and lithium metal, thereby unlocking the potential for high-energy-density ASSLMBs.
In the quest to enhance the safety of lithium-ion batteries, substantial research is underway to develop all-solid-state batteries, facing challenges in achieving high ion
This review provides a concise historical overview of nitride SSEs, followed by a summary of recent key advances in their materials, crystal and local structures, and synthesis methods,
Sulfide-based solid electrolyte films with high room-temperature ionic conductivity will boost the energy density of all-solid-state batteries. This Review covers the
Stabilizing Solid Electrolyte-Anode Interface in Li-Metal Batteries by Boron Nitride-Based Nanocomposite Coating Li1.3Al0.3Ti1.7(PO4)3 (LATP) solid electrolyte is inexpensive, light,
Polyethylene oxide (PEO)-based solid-state polymer electrolytes (SPEs) are limited by their poor cyclic stability and inferior ionic conductivity for applicating in high-safety,
Commercial lithium-ion batteries (LIBs) predominantly rely on liquid electrolytes, which are prone to various safety risks, such as leakage and combustion. Solid-state batteries
Nitride solid-state electrolytes (SSEs) hold significant potential for addressing critical interfacial issues between SSEs and lithium metal in all-solid-state lithium metal batteries.
Abstract Polyethylene oxide (PEO)-based solid-state electrolytes have great potential in the development of solid-state metallic lithium batteries. However, it is difficult to
The Synthesis of Three-Dimensional Hexagonal Boron Nitride as the Reinforcing Phase of Polymer-Based Electrolyte for All-Solid-State Li Metal Batteries Yuhan Ma, Jiaxin Wu,
Request PDF | Fast‐Charging Long‐Life Solid‐State Sodium Metal Batteries Enabled by 2D Boron Nitride Nanosheets Based Quasi‐Solid‐State Electrolytes | Solid‐state
Nitride solid-state electrolytes (SSEs) hold significant potential for addressing critical interfacial issues between SSEs and lithium metal in all-solid-state lithium metal batteries. These batteries are at the forefront of energy storage and materials science, and they promise to revolutionize electric vehicles.
Owing to Li 3N having a high ionic conductivity and being stable against lithium anodes, it is a favorable candidate for SEI construction (Fig. 1c). Furthermore, some organic or inorganic compounds working together with Li3 N may improve the interface to inhibit the growth of lithium dendrites . 3. Properties of lithium nitride
However, the growth of dendrites during electrodeposition still significantly hinders the practical application of lithium metal batteries. Lithium nitride (Li3N) modification of the surfaces of Li anodes is regarded as an effective strategy to suppress the growth of lithium dendrites.
The all-solid-state battery employing an LZC-N0.15 electrolyte and a LiCoO 2 cathode delivers a high discharge capacity of 218.4 mAh g −1 at 4.62 V. All-solid-state lithium batteries are widely regarded as the most promising next-generation energy storage technology due to their exceptional combination of high energy density and intrinsic safety.
The oxidation potential of Li3 N is only 0.5 V , which means that lithium nitride will tend to decompose and thus fail if the electrochemical potential exceeds 0.5 V when matched with an SSE . In this review, many successful cases of constructing Li 3 N-based SEIs/ASEIs on the surfaces of Li metal anodes are summarized carefully.
A series of lithium nitric halides in the Li 3a + b N a X b (X = Cl, Br, or I) systems have been identified as potential candidates for SEIs to prevent detrimental reactions with lithium anodes . The Li 3a + b N a X b systems consist of alternating layers of lithium nitrides and halides.
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